There are certainly facial tattoos which are stored under Accessories as either glasses or more often as costume masks, and which can be applied or removed using mirror options.
Examples here (bottom of page):
http://www.mirkwood-sims.de/genetics2.htmland here:
http://fantasylostworld.online.fr/Sims2/Vetementaccessoire/Sims2AMF.htmIf there is a specific type of tattoo you're after, perhaps it could be located.